That is some very nonesense "experiment", just some dumb reels or whatever they are called.
We don't know anything from the materials they used and their properties.
Actually, you don't see the boiling point here. What we see is the effect of the specific heat capacity: it is the amount of energy (heat) you need to put into a material to increase the temperature of 1 kg material to 1 °C or 1 °K.
For example: water has the 2nd highest specific heat capacity known on Earth! with 4.18 kJ/kg*K -- and this actually means, you need to put 4.18 kJ worth of energy to 1 kg of water to increase its temperature 1 °C (or 1 °K). H2 (hydrogen) has the highest specific heat capacity with 14.3 kJ/kg*K
On the other hand, ethanol has a value of 2.43 kJ/kg*K.
Assuming it is pure Ethanol in the experiment and pure H2O, the temperature of Ethanol will increase much faster and - for sure - start to evaporate earlier and thus, less amount of Ethanol is available and thus, the temperature will start to increase again faster.
if somebody wants to have a look on thermodynamics, please enjoy yourself:
https://en.wikipedia.org/wiki/Specific_heat_capacity