Distilled from oranges, how I make it.

Information about fruit/vegetable type washes.

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EricTheRed
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Re: Distilled from oranges, how I make it.

Post by EricTheRed »

Back to the enzymes

This is what Distillique publishes on their website (not sure if i can post that) - and the one i use - it turned a thick mash of peaches into a watery peach mash. Also used it on grapes.
And it costs R145 (which is less than US$10) - using the worst case scenario, that works out to R0.75 (about US$0.05) per kilo of fruit
so not expensive at all.

Enzyme: Pectolase (Pectolyase) mix for 200 to 400kg fruit

This 50g granular Pectolase mix is suitable to treat between 200 and 400 kg of fruit.

The pectolase mix is used to break down pectin and proto-pecting in fruit to:
  • - increase the juice yield from fruit and to;
  • - prevent methanol formation during fermentation and to;
  • - enhance the amount of fermentable sugars in the fruit.
Mash your fruit with the minimum amount of water and heat to between 40 and 50 degree C
Sprinkle pectolase over mash and stir in well
Leave for 2 hours at temperature between 40 and 50 degree C..
Add water and sugar (if required) to fruit for fermentation only after pectolase treatment.
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NormandieStill
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Re: Distilled from oranges, how I make it.

Post by NormandieStill »

Awesome. I'd be tempted to see if they ship to France. The prices I quoted were for pure (I think) enzymes, which also means that the quantities required for our scale would be exceptionally hard to measure. A prepared formula probably also contains filler of some variety which makes it easier to dose. If the weather doesn't screw up pollination this year, I plan on making a sloe brandy and a plum brandy this autumn and affordable pectolase would make me much happier about it.
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EricTheRed
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Re: Distilled from oranges, how I make it.

Post by EricTheRed »

:D
The cost of shipping to France from RSA would be WAY more than the cost of the product.
H3ll, i sent a single page letter to Bratislava a couple months ago, and that ended up costing almost R1000 (EURO 50)
There must be a local supplier in France somewhere
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Re: Distilled from oranges, how I make it.

Post by NormandieStill »

Since posting I've found several suppliers of Pectolase including Youngs in the UK. I don't know how I missed them before. I'll try and get confirmation that it's definitely pectolase and not a blend. And then I'll see if anyone wants my near untouched bag of pectinase that I bought when I started wine making.
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Re: Distilled from oranges, how I make it.

Post by Hügelwilli »

Hillbilly Popstar,
orange juice contains way less methanol than brandy from high pectin fruits. I google 140mg/lt average in orange juice. And the EU limit for a 40%abv spirit is 5400mg/lt. This limit is surpassed often.
You ask for a study. After I had posted a study. There are many studies. Simply google words like brandy and methanol. A study about fermented whole kumquats you would have to write yourself though. The question is, if I have to prove that it is unsafe or you have to prove it is safe. Normally at least in this forum you have to prove the safety. Like in the plastics discussion for example I cannot say you have to prove food grade silicon being unsafe.


NormandieStill,
I also wondered about the resume of the pdf. Because the tables and the german text tell a different story.
Perhaps you could look at the table on page 3. There are three numbers to each fruit. First number is the methanol content in a fermented must without added enzymes, the second number is with added "new" enzyme and the third number is with added "old" one. Yes, the very low pectin fruits don't show a rise in methanol using the new enzyme, but the high pectin fruits do. And only for high pectin fruits using enzymes makes sense.
Most extreme example: "Quitte Robusta 7150 32850 38350"
And also here in this thread we talk about a high pectin must.
And in picture 3 ("Abb.3") you can see that the new enzyme doesn't liquefy as much as the old one.
A 2001 study tried to establish safe limits and came to a conclusion that up to 2% methanol by volume in a 40% abv drink could be tolerated with a safety factor of 4. The EU limit is set at 0.4% and from memory only certain years production actually came close to exceeding that limit.
The whole text is:
Thus, assuming that an adult consumes
4x25-ml standard measures of a drink containing 40%
alcohol by volume over a period of 2 h, the maximum
tolerable concentration (MTC) of methanol in such a drink
would be 2% (v/v) by volume. However, this value only
allows a safety factor of 4 to cover variation in the volume
consumed and for the effects of malnutrition (i.e., folate
deficiency), ill health and other personal factors (i.e.,
ethnicity). In contrast, the current EU general limit for
naturally occurring methanol of 10 g methanol/l ethanol
[which equates to 0.4% (v/v) methanol at 40% alcohol]
provides a greater margin of safety.
The study shows that it is normally safe to drink a normal amount of a spirit with 5 times higher methanol levels than the EU allows. It doesn't show long time effects.
If I say, I drank a Whisky from a still glued together with silicone and I am feeling fine, is it a prove that silicone is safe? Of course not.

But yes, probably Demys and Hillbilly Popstars brandies are all right, although maybe breaking the EU methanol limits. But I don't think it is wrong to utter those concerns here in Demys thread.


EricTheRed,
is this a study or advertising:
The pectolase mix is used to break down pectin and proto-pecting in fruit to:

- increase the juice yield from fruit and to;

- prevent methanol formation during fermentation and to;

- enhance the amount of fermentable sugars in the fruit.
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Re: Distilled from oranges, how I make it.

Post by EricTheRed »

Hügelwilli asked
EricTheRed,
is this a study or advertising:
As it is on a commerce site, i would call it advertising

However, they are a reputable supplier.
I will email them for more details and post when they reply
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Hügelwilli
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Re: Distilled from oranges, how I make it.

Post by Hügelwilli »

EricTheRed wrote: Thu Mar 10, 2022 2:40 am I will email them for more details and post when they reply
And then we have to decide if we trust a supplier or measured concentrations in a study.
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Demy
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Re: Distilled from oranges, how I make it.

Post by Demy »

Certainly every contribution is precious, it is a free discussion and I would say interesting. I have never used enzymes for fruit, from my readings breaking down pectin by enzymes increases the methanol, except with "liase" enzyme pure. We must consider that the fruits themselves, from what I know, have some of these enzymes themselves and the yeast also produces them, in fact after fermentation the density is reduced. I've only fermented orange juice in the past but I wanted to try something new, ... it's nothing new to ferment whole fruit (even commercially) and my thought is that a stripping and stilling with plates should be pretty safe.
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Re: Distilled from oranges, how I make it.

Post by NormandieStill »

If you really want to make sure then you need to heat to denature the natural enzymes (because you can heat and cool down, but adjusting pH will piss off your yeast. Maybe don't let it sit too long after fermentation before distilling in case the enzymes keep working despite the abv.
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Re: Distilled from oranges, how I make it.

Post by Hügelwilli »

Demy wrote: Thu Mar 10, 2022 5:31 am Certainly every contribution is precious, it is a free discussion and I would say interesting. I have never used enzymes for fruit, from my readings breaking down pectin by enzymes increases the methanol, except with "liase" enzyme pure.
According to the table in the study this is wrong.
Demy wrote: Thu Mar 10, 2022 5:31 am it's nothing new to ferment whole fruit (even commercially)
Fermenting whole citrus fruits is new and it is sure that there is more pectin in it than in other whole fruits typical used for brandy.
Demy wrote: Thu Mar 10, 2022 5:31 am and my thought is that a stripping and stilling with plates should be pretty safe.
Perhaps you could teach the European professional distillers how to do it.

One thing where I really think that Demys brandy perhaps is safe, is, because he adds sugar, he reduces the methanol amount per ethanol. Adding sugar dilutes congeners with ethanol.
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Re: Distilled from oranges, how I make it.

Post by EricTheRed »

a little research turned up this
https://en.wikipedia.org/wiki/Pectin_lyase
https://pubmed.ncbi.nlm.nih.gov/17263548/
the easiest reading one is
https://encyclopedia.pub/10419

In short, the way i understand it - the Pectin-Lyase enzyme inhibits methanol production
AND
heating to high enough temperature denaturizes the enzymes responsible for methanol production.

Since most of the time I boil the fruit mashes (except grape at least for me), to soften them up to be able to get the stones and seeds out easily, methanol production potential is reduced. The adding of the Lyase enzyme breaks it down further.

I think it is important to know the names of the enzymes are important - Esterlyase produces methanol, while pectic-lyase inhibits it.

If i got it wrong, then i will stand corrected.
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Hügelwilli
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Re: Distilled from oranges, how I make it.

Post by Hügelwilli »

Eric,
in the first link they say that this enzyme doesn't produce methanol. But they don't say it inhibits the methanol production.
From the second link I can only read the abstract for free.
The third link quotes studies that may say that it inhibits methanol. I don't want to spend my time to search for those studies.

What is sure and we all agree I think is that pectin has methyl groups. Sometimes more, sometimes less. If something sets them free, we get methanol. The new enzyme doesn't attack the linkages to the methyl groups, that's a good thing.
But it is not plausible that it hinders other enzymes to do it. Actually according to the table of the study I posted it promotes other enzymes to do it.

Heating up a fruit must before fermentation causes loss of aroma. I know, also tried and true fruit recipes here using heating the fruits. But it is something English speaking countries homedistiller related. In Europe, where the famous fruit brandies come from, no one does it. Like wine, musts are always fermented without cooking.
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Re: Distilled from oranges, how I make it.

Post by Demy »

NormandieStill wrote: Thu Mar 10, 2022 5:58 am If you really want to make sure then you need to heat to denature the natural enzymes (because you can heat and cool down, but adjusting pH will piss off your yeast. Maybe don't let it sit too long after fermentation before distilling in case the enzymes keep working despite the abv.
Yes, I have read many articles talking about heating to disregard enzymes, distil immediately after fermentation etc. .. all things I do already .. the only thing I found not very practicable is the low pH that I find in any studios, it seems Be around 2.5 and I think the yeast is not happy at these levels.
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Re: Distilled from oranges, how I make it.

Post by Demy »

Hügelwilli wrote: Thu Mar 10, 2022 10:08 am
Heating up a fruit must before fermentation causes loss of aroma. I know, also tried and true fruit recipes here using heating the fruits. But it is something English speaking countries homedistiller related. In Europe, where the famous fruit brandies come from, no one does it. Like wine, musts are always fermented without cooking.
Right. I have not seen producers that heat fruit puree, sometimes I tried and I must say that the aroma is affected, seems to be switched off than fruit unheated.
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Re: Distilled from oranges, how I make it.

Post by Demy »

Some interesting readings I had done in the past
https://encyclopedia.pub/10419
https://www.intechopen.com/chapters/54078 (Interesting about half item)
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Re: Distilled from oranges, how I make it.

Post by psf »

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8125215/

I only went to searching and reading after reading this thread to educate myself. I don't understand the enzyme portion of it and I just focused on the parts where it talked about mitigation. Just sharing what I read.

It states that there is more methanol in the tails since methanol is more soluble with water than ethanol and recommends not taking any hearts past 50% and not recycling the tails. There are several other mitigating factors i.e. reflux, double distill, acidic mash during ferment.
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Re: Distilled from oranges, how I make it.

Post by Demy »

psf wrote: Thu Mar 10, 2022 1:47 pm https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8125215/

I only went to searching and reading after reading this thread to educate myself. I don't understand the enzyme portion of it and I just focused on the parts where it talked about mitigation. Just sharing what I read.

It states that there is more methanol in the tails since methanol is more soluble with water than ethanol and recommends not taking any hearts past 50% and not recycling the tails. There are several other mitigating factors i.e. reflux, double distill, acidic mash during ferment.
Yes, that's right, all of the things I mentioned earlier in the discussion. The point is the alcohol content, ... with a low alcohol content (ferment) the separation is very difficult and skips the boiling point separation method, but with a high ABV in the boiler things change. This is why I said stripping + column distillation from the beginning. Not being laboratory scholars we should consider these studies in the absence of anything else, of course even the studies can be imperfect for the many variables.
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Re: Distilled from oranges, how I make it.

Post by Demy »

Another interesting document i had found not long ago
preprints202103.0731.v1.pdf
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Re: Distilled from oranges, how I make it.

Post by NormandieStill »

Demy wrote: Sat Mar 12, 2022 10:04 am Another interesting document i had found not long ago
preprints202103.0731.v1.pdf
That was the one I found and posted here I think. That was how I learnt about the difference between pectinase and pectolyase.
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