I finally got around to testing this myself, using gin, because a) I love gin, and b) many of the herbal characters in gin are similar to the hop characters sulfates are used to emphasize in beers such as IPAs (e.g. citrus, pine, and resin notes).
My approach was simple, I made my standard gin using an airstill:
- 1L of 50% ABV grain spirit
- 35 g juniper berries, half lightly crushed, half whole
- 8 g mixed fresh citrus zest
- 7 g coriander, lightly crushed
- 0.7 g Angelica root
Once the raw distillate was collected, I diluted it to 42% with grocery store distilled water, split the distillate into thirds, and added:
- Nothing
- 0.35 g/L gypsum (~80 PPM calcium & ~200 PPM sulfate)
- 0.4 g/L calcium chloride (~110 PPM calcium & ~200 PPM chloride)
As straight gin, all the high-gypsum was night-and-day different (we both identified the high-sulfate gin 3 in 3 tries), while the water and calcium samples were different, but not hugely so (we could tell these apart 2 of 3 (me), and 3 of 3 (wife) tries).
Chloride did not do much; the spirit felt a little "rounder" in the mouth, and some of the "sharper" edges on the pine notes were softened, relative to the pure water control. Subtle, but noticeable if you knew to look for the differences. I'm not convinced that someone would notice the differences if they weren't aware of what they were supposed to look for.
The gypsum samples were very different. The gypsum amplified the citrus notes of the coriander and zest, and brought out more of the "berry" note of the juniper. The bitterness was also more apparent, but not in an unpleasant way. In my opinion (I like intense gins), the addition of gypsum greatly improved the flavour of the gin - more intense, and more citrus. My wife was the opposite, and thought things were too intense for her tastes.
A few days (and a hangover) later we did triangle tests, using these gins in gin and tonics...and couldn't tell the difference between any of them. The dilution of the minerals into the tonic, plus the flavour of the tonic, completely removed any detectable differences between the gins.
Anyways, it was a fun little experiment that I thought people here would find interesting.