Lactone: Difference between revisions

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Lactones contribute to the flavor profile of whiskeys and other beverages aged in oak barrels.  
[[File:Whiskey lactone glass.gif|thumb|280px|right|This is the chemical structure of a Whiskey Lactone on a glass of Whiskey.]]
[[File:Whiskeylactonetimechart.jpg|thumb|280px|right|Lower toast levels increase the whiskey lactone levels. ]]
Lactones contribute to the flavor profile of [[whiskey]]s and other beverages [[aged]] in [[oak barrel]]s.  


Lactones contribute significantly to the flavor of fruit, and of unfermented and fermented dairy products,[9] and are therefore used as flavors and fragrances.[3] Some examples are γ-decalactone (4-decanolide), which has a characteristic peach flavor;[9] δ-decalactone (5-decanolide), which has a creamy coconut/peach flavour; γ-dodecalactone (4-dodecanolide), which also has a coconut/fruity flavor,[9] a description which also fits γ-octalactone (4-octanolide),[10] although it also has a herbaceous character;[9] γ-nonalactone, which has an intense coconut flavor of this series, despite not occurring in coconut,[11] and γ-undecalactone.
The 3S,4S isomer (cis-3-Methyl-4-octanolide), commonly known as whisky lactone or quercus lactone is an important ingredient in the aroma of whiskey (where it was first identified by Suomalainen and Nykänen in 1970),and other alcoholic beverages that have been aged in oak barrels. It is sometimes added to the liquor as a flavoring agent. It has a coconut, celery or fresh wood aroma, that can be detected by humans at the concentration of 1 μg/L in air.[5] A mixture of the cis and trans isomers is repellent for mosquitos and flies.
 
Lactones contribute significantly to the flavor of [[fruit]], and of unfermented and [[fermented]] dairy products, and are therefore used as flavors and fragrances. Some examples are γ-decalactone (4-decanolide), which has a characteristic [[peach]] flavor; δ-decalactone (5-decanolide), which has a creamy coconut/peach flavour; γ-dodecalactone (4-dodecanolide), which also has a coconut/fruity flavor, a description which also fits γ-octalactone (4-octanolide), although it also has a herbaceous character; γ-nonalactone, which has an intense coconut flavor of this series, despite not occurring in coconut, and γ-undecalactone.


Macrocyclic lactones (cyclopentadecanolide, 15-pentadec-11/12-enolide) have odors similar to macrocyclic ketones of animal origin (muscone, civetone), but they can be prepared more easily, for example, by depolymerization of the corresponding linear polyesters. Replacement of a methylene unit by oxygen barely affects the odor of these compounds, and oxalactones with 15 – 17-membered rings are produced in addition to cyclopentadecanolide (e. g., 12-oxa-16-hexadecanolide).[3]


==External links==
==External links==
* [https://en.wikipedia.org/wiki/Lactone Lactone on Wikipedia]
*[https://en.wikipedia.org/wiki/Lactone Lactone on Wikipedia]
*[https://en.wikipedia.org/wiki/Cis-3-Methyl-4-octanolide Whiskey Lactone on Wikipedia]
 
 
[[Category:Maturation]]
[[Category:Glossary]]

Latest revision as of 12:20, 12 October 2017

This is the chemical structure of a Whiskey Lactone on a glass of Whiskey.
Lower toast levels increase the whiskey lactone levels.

Lactones contribute to the flavor profile of whiskeys and other beverages aged in oak barrels.

The 3S,4S isomer (cis-3-Methyl-4-octanolide), commonly known as whisky lactone or quercus lactone is an important ingredient in the aroma of whiskey (where it was first identified by Suomalainen and Nykänen in 1970),and other alcoholic beverages that have been aged in oak barrels. It is sometimes added to the liquor as a flavoring agent. It has a coconut, celery or fresh wood aroma, that can be detected by humans at the concentration of 1 μg/L in air.[5] A mixture of the cis and trans isomers is repellent for mosquitos and flies.

Lactones contribute significantly to the flavor of fruit, and of unfermented and fermented dairy products, and are therefore used as flavors and fragrances. Some examples are γ-decalactone (4-decanolide), which has a characteristic peach flavor; δ-decalactone (5-decanolide), which has a creamy coconut/peach flavour; γ-dodecalactone (4-dodecanolide), which also has a coconut/fruity flavor, a description which also fits γ-octalactone (4-octanolide), although it also has a herbaceous character; γ-nonalactone, which has an intense coconut flavor of this series, despite not occurring in coconut, and γ-undecalactone.


External links